New Organic Dye-Sensitized Photovoltaic Cell for Simultaneous Photon Energy Capture, Conversion, and Storage

Overview

Objectives/Goals To modify Grätzel type blackberry anthocyanin dye-sensitized photovoltaic cells and to improve the ability of the cell to simultaneously capture, convert, and store photon energy. Methods/Materials Grätzel type photovoltaic cells were made with ITO glass and KI/I electrolyte. Control cells had one electrode composed of a mesoporous titanium dioxide layer with absorbed blackberry anthocyanin dye and a graphite catalyst electrode. Modified cells included additional porous layers of silica gel on either or both control electrodes, the twin layers separated by tissue paper. Trial modifications also included carbon black or mixtures of carbon black and silica gel in layers on the control electrodes. Control and modified cells were tested for photovoltaic effect under halogen light and in darkness. Results All cells showed an ability to convert photon energy into electrical energy. After halogen light charging and storage in darkness, control cells showed energy supply with weak no load power of 2.25x10^-11 W/cm^2. The no load power of silica gel modified cells under similar dark conditions was 1.4x10^-9 W/cm^2, with maximum recorded power of 6x10^-8 W/cm^2 under load. Cells with carbon black layers showed a reversal of electrode potential in light and dark conditions. Conclusions/Discussion Organic dye-sensitized photovoltaic cells can capture, convert, and store photon energy. The storage capacity of standard Grätzel type photovoltaic cells is low as indicated by power under no load. This poor storage is attributed to the low amount of electrolyte and to the absence of sufficient dielectric material in the standard cell. The power capacity can be increased by modifying a standard cell using mesoporous silica gel layers on both electrodes with a porous paper separator. This modification potentially increases the amount of electrolyte and the amount of dielectric material in the cell, leading to improved storage capacity.

Awards (1)

• Category Award

Competition history

• CSEF 2005 Electricity & Electronics · Entry S0707

Resources

• CSEF project summary ↗

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